SANSHER CORP -- DAD'S EASY SPRAY REMOVER -- 6850-00N062266
===================== Product Identification ===================== Product ID:DAD'S EASY SPRAY REMOVER MSDS Date:10/15/1991 FSC:6850 NIIN:00N062266 === Responsible Party === Company Name:SANSHER CORP Address:8005 N CLINTON ST City:FORT WAYNE State:IN ZIP:46825 Country:US Info Phone Num:219-484-2000 Emergency Phone Num:219-484-2000 Preparer's Name:PHILIP BRADLEY CAGE:JO095 === Contractor Identification === Company Name:SANSHER CORP Address:8005 N CLINTON ST Box:City:FORT WAYNE State:IN ZIP:46825 Country:US Phone:219-484-2000 CAGE:JO095 ============= Composition/Information on Ingredients ============= Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2000-4000 MG/KG. CAS:75-09-2 RTECS #:PA8050000 OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 OSHA PEL:200 PPM, S ACGIH TLV:200 PPM;250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA) (MFR'S INVALID CAS #108-88-2) CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL BUTYL ETHER) CAS:111-76-2 RTECS #:KJ8575000 OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:SUPP DATA:FROM DHHS (NIOSH) PUBLICATION NO.90-118 . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:EXCESS INHAL/INGEST MAY PRDCE SYMPS OF CNS DEPRESS, LT HEAD TO UNCON/DEATH. CHRONIC:CAN CAUSE HDCH, MENTAL CONFUSN, DEPRESS, NAUS, DIZZ, VOMIT, COUGH, DERM, LIVER/KIDNEY DMG. CHLOROCARBON MATLS HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS, SUPP, VOL 7, PG 194, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC (SUPDAT) Effects of Overexposure:HLTH HAZ:ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . NOTE:TOLUENE APPEARS ON NAVY LIST OF OCC UP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE (SUP DAT) Medical Cond Aggravated by Exposure:PERSONS W/ANGINA OR OTHER CARDIOVASCULAR DISEASE SHOULD NOT BE EXPOSED TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:SKIN:FLUSH W/WATER. INHAL:MOVE TO FRESH AIR, CALL MD. INGEST:DO NOT INDUCE VOMITING, CALL MD. EYES:IRRIGATE W/WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:>104F,>40C Lower Limits:14% Upper Limits:25% Extinguishing Media:CO*2, FOAM, DRY POWDER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCLUDE HCL & PHOSGENE . EXCESSIVELY HIGH TEMPS & OPEN FLAME WILL PRDCE HYDROGEN CHLORIDE PLUS OTHER TOX VAPS SUCH AS PHOSGENE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS:MOP UP, WIPE UP OR SOAK UP IMMEDIATELY. REMOVE TO OUT OF DOORS. LARGE SPILLS:EVACUATE AREA. CONTAIN LIQUID; TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF WATER SUPPLY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:EXCERCISE REAS CARE & CAUT. STORE CNTNRS IN COOL, DRY, WELL VENTILATED AREA. CONC VAPS OF THIS PROD ARE HVR/AIR & WILL COLLECT IN LOW AREAS. Other Precautions:USE THIS PROD OUTDOORS, IF POSSIBLE. NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES & HOT SURFACES. HEAT &/OR UV RADIATION MAY CAUSE FORMATION OF HCL &/OR PH OSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR SOLVENT VAPORS. Ventilation:LOCAL EXHAUST:PROVIDE ADEQUATE VENTILATION. MECHANICAL (GENERAL):MOVING FRESH AIR OVER WORK AREA. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . PROTECTIVE APRON. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LUNG, LIVER, SALIVARY, MAMMARY GLAND (TUMORS). EFTS OF OVEREXP:HNDLG & EXPOS INFO . ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HE MATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:104F,40C Vapor Pres:350 @ 20C Vapor Density:2.93 Evaporation Rate & Reference:14.5 (BUTYL ACETATE=1) Solubility in Water:RINSEABLE Appearance and Odor:CLEAR LIQUID; LOW CHARACTERISTIC ODOR AT 70F. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SODIUM, POTASSIUM & MAGNESIUM, ALUMINUM STORAGE CONTAINERS. Stability Condition to Avoid:EXCESSIVE HIGH TEMPERATURE, OPEN FLAMES, EXCESSIVE HYDROLYSIS. Hazardous Decomposition Products:EXPOSURE TO OPEN FLAMES GENERATE HYDROGEN CHLORIDE & SMALL AMOUNT OF PHOSGENE & CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SEND TO LICENSED, PERMITTED INCINERATORS OR EVAPORATE VERY SMALL QUANTITIES IN COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS. 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