J T BAKER INC -- ETHYLENEDIAMINE -- 6810-00-101-7203
===================== Product Identification ===================== Product ID:ETHYLENEDIAMINE MSDS Date:09/10/1986 FSC:6810 NIIN:00-101-7203 === Responsible Party === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:908-859-2151 Emergency Phone Num:908-859-2151, OR 800-424-8802 CAGE:DO803 === Contractor Identification === Company Name:J T BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:1-800-582-2537 CAGE:DO803 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENEDIAMINE (SARA III) CAS:107-15-3 RTECS #:KH8575000 Fraction by Wt: 90-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:S, 10 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 IS 1160 MG /KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:PRODUCT IS CORROSIVE TO BODY TISSUES, IS TOXIC AND MAY BE ABSORBED THROUGH THE SKIN. CHRONIC EFFECTS ARE LIVER AND/OR KIDNEY DAMAGE. Explanation of Carcinogenicity:COMPOUND IS ALSO NOT ON 'Z' LIST. Effects of Overexposure:VAPORS ARE IRRITATING TO EYES, SKIN, MUCOUS MEMBRANES. INHALATION:NAUSEA, VOMITING, HEADACHE, LIGHT HEADEDNESS. LIQUID MAY CAUSE BURNS TO SKIN & EYES. SUBSTANCE IS READILY ABSORBED THROUGH SKIN, AND MAY CAUSE SKIN SENSITIZATION. INGESTED:NAUSEA, VOMNITING, G/I IRRITATION, AND BURNS TO MOUTH OR THROAT. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:**CALL A PHYSICIAN!** INGESTED:DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, MILK OF MAGNESIA. INHALED:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION OR OXYGEN IF NEEDED. CONTACT:FLUSH E YES OR SKIN WITH PLENTY OF WATER FOR ATLEAST 15 MINUTES WHILE REMOVING ANY CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=34.C, 93.2F Autoignition Temp:Autoignition Temp Text:UNKNON Lower Limits:4.2 Upper Limits:14.4 Extinguishing Media:USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA W/ FULL FACEPIECE AND PROPER PROTECTIVE CLOTHING. MOVE CONTAINERS FROM EXPOSURE IF W/O RISK. COOL FIRE EXPOSED CONTAINERS W/ WATER. Unusual Fire/Explosion Hazard:VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCE AND FLASH-BACK. CLOSED CONTAINERS MAY EXPLODE IF HEATED. CONTACT W/ STRONG OXIDIZERS MAY CAUSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SCBA & PROTECTIVE CLOTHING. SHUT OF IGNITION SOURCES. STOP LEAK IF W/O RISK. USE WATRER TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSSTABLE MATERIAL AND PLACEINTO CONTAINER FOR DISPOSAL . FLUSH AREA WITH WATER. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY SUPPLIER ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:GROUND CONTAINERS WHEN TRANSFERRING LIQUID, ESPECIALLY FOR 5 GALLON LARGER CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS TO 500PPM CHEMICAL CARTRIDGE RESPIRATOR WITH AMMONIA/AMINE CARTRIDGE. ABOVE 500PPM USC SCBA. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:BUTYL RUBBER Eye Protection:SAFETY GOGGLES AND FACE SHIELD Other Protective Equipment:UNIFORM, PROTECTIVE SUIT RECOMMENDED. HMIS:EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:HMIS: USE STRICT CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health MFR DID NOT LIST ANY HYGENIC WORK PRACTICES. MSDS RECEIVED FROM NAVY (FOCAL POINT N). NAVY IDENTIFIED NSN. ================== Physical/Chemical Properties ================== HCC:F7 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=117.2C, 243.F Melt/Freeze Pt:=11.C, 51.8F Vapor Pres:10 MM Vapor Density:2.07 Spec Gravity:0.90 Evaporation Rate & Reference:0.91 BUTYL ACETATE=1 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS THICK CLEAR LIQUID WITH AMMONIA ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZERS, HALOGEN ACIDS, HALOGEN COMPOUNDS, COPPER & ITS ALLOYS, COPPER SALTS Stability Condition to Avoid:HEAT FLAME AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL REGULATIONS. RCRA HAZARDOUS WASTE NUMBER IS D001, D002. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.