J.T. BAKER COMPANY -- POTASSIUM HYDROXIDE -- 6810-00-136-6000
===================== Product Identification ===================== Product ID:POTASSIUM HYDROXIDE MSDS Date:01/24/1994 FSC:6810 NIIN:00-136-6000 === Responsible Party === Company Name:J.T. BAKER COMPANY Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865-2219 Country:US Info Phone Num:201-859-2151 Emergency Phone Num:201-859-2151 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 85-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 365 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:CHRONIC EFFECTS: LUNG DAMAGE. Explanation of Carcinogenicity:NONE IDENTIFIED. Effects of Overexposure:INHALATION-SEVERE IRRITATION OR BURNS OF RESPIRATORY SYSTEM, ULCERATION OF MUCOUS MEMEBRANES. SKIN-SEVERE BURNS. EYE-SEVERE BURNS, PERMANENT EYE DAMAGE. INGESTION-SEVERE BURNS TO MOUTH, THROAT AND STO MACH, & MAY BE FATAL. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGESTION-CALL A PHYSICIAN. DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER, THEN DILUTED VINEGAR, FRUIT JUICE OR EGG WHITES BEATEN WITH WATER. INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING, PERFORM CPR. IF BREATHING ISHARD, GIVE OXYGEN. SKIN-FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING SOILED CLOTHING. EYE-FLUSH WITH WATER FOR AT LEAST 15 MIN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:A VIOLENT EXOTHERMIC REACTION OCCURS WITH WATER. SUFFICIENT HEAT MAY BE PRODUCED TO IGNITE COMBUSTIBLE MATERIALS. REACTS WITH MOST METALS TO FORM HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NEUTRACIT-2 OR BACAIM CAUSTIC NEUTRALIZERS ARE RECOMMENDED FOR SPILL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE IN CORROSION PROOF AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:NOTE: WHEN MIXING WITH WATER, ALWAYS ADD CAUSTIC SLOWLY TO WATER. CONTINNOUSLY STIR SOLUTION TO MINIMIZE SPATTERING. NEVER ADD WATER TO CAUSTIC. MATERIAL IS HYGROSCOPIC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATIONS EXCEED TLV. AT CONCENTRATIONS UP TO 43 PPM,,, A HIGH-EFFICIENCY PARTICULATE RESPIRATOR IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BRE ATHING APPARATUS IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED. Eye Protection:SAFETY GOGGLES ARE RECOMMENDED. Other Protective Equipment:UNIFORM, APRON ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health CORROSIVE. ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:2408F,1320C Melt/Freeze Pt:M.P/F.P Text:680F,360C Spec Gravity:2.04 pH:14 Solubility in Water:APPRECIABLE (>10%) Appearance and Odor:WHITE TO LIGHT YELLOW PELLETS. ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, STRONG ACIDS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, ZINC, ALUMINUM, TIN, CARBON DIOXIDE. Stability Condition to Avoid:MOISTURE, HEAT. Hazardous Decomposition Products:HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.