FISHER SCIENTIFIC, CHEMICAL DIV. -- PHENOL, LIQUID -- 6810-01-227-9587
===================== Product Identification ===================== Product ID:PHENOL, LIQUID MSDS Date:05/08/1995 FSC:6810 NIIN:01-227-9587 === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 OR 201-796-7523 Emergency Phone Num:201-796-7100/800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO Address:2000 PARK LN Box:City:PITTSBURGH State:PA ZIP:15275 Country:US Phone:412-490-8586 CAGE:22527 Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL (SARA 302/313) (CERCLA) CAS:108-95-2 RTECS #:SJ3327000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 317 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: CORROSIVE IF INHALED, SKIN & EYE CONTACT. HIGHLY TOXIC BY INHALATION, TOXIC BY DERMAL ABSORPTION & INGESTION. MAY CAUSE SEVERE CNS DEPRESSION IF VAPORS/MIST INHALED; LIQUID ON SKIN ABSORPTION; INGESTED. EYE CONTACT MAY CAUSE SEVERE IRRITATION/DAMAGE/BLINDNESS. CHRONIC: SEE SUPPLEMENTAL...... Explanation of Carcinogenicity:IARC LISTS PHENOL IN CANCER GROUP 3-INSUFFICIENT HUMAN/LIMITES ANIMAL EVIDENCE. Effects of Overexposure:INHALED/INGESTED/SKIN ABSORPTION-SEVERE IRRITATION OF MUCOUS MEMBRANES, PROFUSE SWEATING, HEADACHE, INTENSE THIRST, NAUSEA, VOMITING, ABDOMINAL PAIN, DIARRHEA, SALAVATION, CYANOSIS, TINNITUS, TWITCHIN G, TREMORS, CONVULSIONS. SKIN CONTACT-BURNS, WHITE-YELLOWISH-BROWN COLOR. EYES-PAIN, REDNESS, BLURRED VISION. Medical Cond Aggravated by Exposure:PERSONS WITH CONVULSIVE DISORDERS AND ABNORMALITIES OF THE SKIN, RESPIRATORY TRACT, LIVER, AND KIDNEYS. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL ATTENTION IN ALL CASES. EYES-IMMEDIATELY FLUSH WITH WATER FOR 30-60 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTE R OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. INGESTED-CONTACT POISON CONTROL CENTER AND OBTAIN IMMEDIATE MEDICAL ATTENTION. ONLY IF NO CORROSIVE INJURY, USE GASTRIC LAVGE OR EMESIS TO CLEAR. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:175F,79C Autoignition Temp:Autoignition Temp Text:1319F Lower Limits:1.8 Upper Limits:8.6 Extinguishing Media:WATER FOG, DRY CHEMICAL, FOAM. FOR LARGER FIRES USE WATER SPRAY, FOG, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF CAN BE DONE AT NO RISK. FIGHT FIRE FROM A DISTANCE. DIKE FIRE-CONTROL WATER FOR LATER DISPOSAL; DO NOT SCATTER THE MATERIAL. Unusual Fire/Explosion Hazard:MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME.VAPOR-AIR MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT.VAPORS ARE HEAVIER THAN AIR,TRAVEL TO DISTANT IGNITION SOURCE ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAAL. STOP LEAK IF NO RISK.USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER INERT MATERIAL AND PLACE IN CONTAINERS FOR LATER DISPOSAL. KEEP UNECESSARY PEOPLE AWAY . ISOLATE & DENY ENTRY. VENTILATE CLOSED SPACES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED PLACE AWAY FROM SOURCES OF IGNITION AND INCOMPATIBLE MATERIALS. Other Precautions:OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS WHEN STORING OR HANDLING PRODUCT. MAY BURN BUT DOES NOT READILY IGNITE. CONTAINERS MAY EXPLODE IN FIRE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:PROCESS ENCLOSURE VENTILATION RECOMMENDED TO MEET PUBLISHED EXPOSURE LIMITS. EQUIPMENT MUST BE EXPLOSION-PROOF. Protective Gloves:IMPERVIOUS-NEOPRENE, PVA, VITON. Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES. Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT ANY POSSIBILITY OF SKIN CONTACT. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health CHRONIC: PROLONGED OR REPEATED EXPSOURE MAY CAUSE SKIN DISRUPTIONS, LIVER/KIDNEY/CNS DAMAGE, DEMATITIS, SKIN SENSITIZATION, CONJUCTIVITIS. OTHER PROTECTIVE EQUIPMENT CONT'D: EYE WASH STATION & SAFETY SHOWER. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:360F,182C Melt/Freeze Pt:M.P/F.P Text:109F,43C Vapor Pres:0.35 Vapor Density:3.2 Spec Gravity:1.0576 pH:6 Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1) Solubility in Water:MODERATE Appearance and Odor:COLORLESS LIQUID; TARRY ODOR AND A SHARP BURNING TASTE. Percent Volatiles by Volume:6.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS+ALLOYS,ALKALIES,ALDEHYDES,CALCIUM HYPOCHLORITE,STRONG OXIDIZING AGENTS,PLASTICS/RUBBER/COATINGS,SODIUM NITRATE... Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: KEEP AWAY FROM SOURCES OF IGNITION AND INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER U118 MAY APPLY TO UNUSED/UNCONTAMINATED PRODUCT. SARA III SECTION 304 RQ=1000 POUNDS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.