INGESTION: Not expected to be harmful under normal conditions of
use.
INHALATION: May be harmful if inhaled. Liquid or vapor may cause
irritation of nose, throat and lungs.
Can cause central nervous system depression.
SKIN: Causes irritation.
EYES: Causes irritation.
Acetone 67-64-1
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
even asphyxiation.
Propane 74-98-6
This material is a simple asphyxiant. Signs and symptoms of
overexposure include cyanosis, respiratory distress, headache,
dizziness, drowsiness, unconsciousness and asphyxiation. Can cause
central nervous system depression.
2-Methylpentane 107-83-5
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting and drowsiness.
Pentane 109-66-0
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
even asphyxiation.
Dimethyl Ether 115-10-6
Can cause central nervous system depression. Signs and symptoms may
include headache, dizziness, nausea, vomiting, unconsciousness and
even asphyxiation.
Acetone 67-64-1
Ingestion may cause liver damage.
Ingestion may cause kidney damage.
-- See Footnote C.
Footnote C: As of the date of issuance of this document, this
material has not been listed by NTP, classified by IARC nor regulated
by OSHA as a carcinogen.
4. First Aid Measures
INGESTION: If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing,
give artificial respiration, preferably mouth-to-mouth.
Call a physician.
SKIN: Flush with plenty of water. Remove contaminated
clothing. Call a physician if irritation persists.
EYES: Immediately flush eyes with plenty of water for at
least 15 minutes. Eyelids should be held apart during
irrigation to insure water contact with entire surface of
eyes and lids. Call a physician.
5. Fire Fighting Measures
Autoignition Temperature Not available
Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol 18.0/1.0
Flash Point -156 deg F (pensky-martens c.c.)
EXTREMELY FLAMMABLE.
DO NOT INCINERATE (BURN) CONTAINER. AVOID HEAT. KEEP CONTAINER
BELOW 120 F (50 C). High temperatures may cause bursting. Do not
place container on radiator, stove, in direct sunlight or near other
heat sources. DO NOT PUNCTURE CONTAINER. Contents under pressure
will discharge. AVOID OPEN FLAMES, SPARKS, PILOT LIGHTS. DO NOT
SMOKE. Vapor may ignite explosively. Spray mist or vapor
evaporating from a deposited film is heavier than air and may settle
in low places or travel outward to a source of ignition and flashback.
In case of fire, use dry chemical, foam or CO2. Water may be
ineffective, but should be used to keep fire-exposed containers cool.
6. Accidental Release Measures
Eliminate all ignition sources. Soak up with absorbent material and
remove to a chemical disposal area. Prevent entry into natural bodies
of water.
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene and safety
practices. These practices include avoiding unnecessary exposure and
removal of the material from eyes, skin and clothing.
Wash thoroughly after handling. Always use appropriate Personal
Protective Equipment (PPE).
INHALATION: USE WITH ADEQUATE VENTILATION. To avoid breathing
vapors or spray mist, open windows and doors or use other means, such
as an exhaust fan to ensure fresh air entry during application and
drying. If you experience eye watering, headache or dizziness,
increase fresh air, wear respiratory protection (NIOSH/MSHA TC23C or
equivalent), or leave the area.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
7.2 Storage
Store in a cool, well-ventilated area.
Store in cool, dry area away from sun, heat, oxidizing materials
and alkaline materials.
Keep containers tightly closed.
Do not store at temperatures above 50 C.
Keep away from heat, sparks, flame and other ignition sources.
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may
be used to effectively minimize employee exposure: local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations. We,
therefore, recommend that you consult with experts of your choice to
determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or
handled, sufficient ventilation in volume and air flow patterns should
be provided to keep air contaminant concentration levels below
acceptable criteria.
8.2 Personal Protection
Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA
approved respiratory protection equipment. Respirators should be
selected based on the form and concentration of contaminants in air
in accordance with OSHA laws and regulations or other applicable
standards or guidelines, including ANSI standards regarding
respiratory protection. Use goggles if contact is likely. Wear
impervious gloves as required to prevent skin contact.
8.3 Exposure Guidelines
Acetone 67-64-1
ACGIH TLV: 500 ppm (1188 mg/m³) TWA; 750 ppm (1782 mg/m³) STEL
OSHA PEL: 1000 ppm (2400 mg/m³)TWA
REMANDED PEL: 750 ppm (1800 mg/m³) TWA; 1000 ppm (2400 mg/m³) STEL
OSHA 1989 PEL remanded, but in effect in some states
Propane 74-98-6
ACGIH TLV: 2500 ppm (4508 mg/m³) TWA
OSHA PEL: 1000 ppm (1800 mg/m³) TWA
Isobutane 75-28-5
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
2-Methylpentane 107-83-5
ACGIH TLV: HexIso.500ppm(1760mg/m³)TWA;1000ppm(3500mg/m³)STEL
OSHA PEL: REMANDED PEL: HexIso.500ppm(1800mg/m³)TWA;1000ppm(3600mg/m³)STEL
OSHA 1989 PEL remanded, but in effect in some states
Pentane 109-66-0
ACGIH TLV: 600 ppm (1770 mg/m³) TWA
OSHA PEL: 1000 ppm (2950 mg/m³) TWA
REMANDED PEL: 600 ppm (1800 mg/m³) TWA; 750 ppm (2250 mg/m³)STEL
OSHA 1989 PEL remanded, but in effect in some states
Dimethyl Ether 115-10-6
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
9. Physical and Chemical Properties
Percent Volatiles 82.5
pH @ 25 C Not applicable
Specific Gravity 0.69
Appearance White to off white in color
Autoignition Temperature Not available
Boiling Point -44 - 150 deg F
Vapor Density (Air=1) > 1
Vapor Pressure, mm Hg @ 20 C Not determined
Evaporation Rate (Butyl Acetate=1) >1
Upper/Lower Flammable Limits Not available
Up/Lower Explosive Limits, % by Vol 18.0/1.0
Flash Point -156 deg F (pensky-martens c.c.)
Freezing Point Not available
Odor Mint when wet
Odor Threshold, ppm Not available
Solubility in Water Negligible
Coefficient of Water/Oil Distrib. Not applicable
10. Stability and Reactivity
Normally stable as defined in NFPA 704-12(4-3.1).
Strong oxidizers.
- Decomposition products may include:
Oxides of carbon.
- Hazardous polymerization:
Will not occur.
None known to company.
11. Toxicological Information
See Section 3 Hazards Identification information.
Acetone 67-64-1
LC50: Not available
LD50: oral-rat=5800 mg/kg (RTECS); skin-rabbit=20 g/kg (RTECS)
Propane 74-98-6
LC50: Not available
LD50: Not available
Isobutane 75-28-5
LC50: Not available
LD50: Not available
2-Methylpentane 107-83-5
LC50: Not available
LD50: Not available
Pentane 109-66-0
LC50: Not available
LD50: Not available
Dimethyl Ether 115-10-6
LC50: Not available
LD50: Not available
12. Ecological Information
Not determined.
13. Disposal Considerations
Dispose of according to local, state/provincial, and federal
requirements.
Empty container: May contain explosive vapors. DO NOT cut, puncture
or weld on or nearby. Incineration will cause container to burst
violently.
14. Transport Information
14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
ORM-D Consumer Commodity.
14.2 Canadian Transportation of Dangerous Goods (TDG)
Not determined.
15. Regulatory Information (Selected Regulations)
15.1 U.S. Federal Regulations
- OSHA Hazard Communication Standard 29CFR1910.1200
This material is a "health hazard" and/or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.
- SARA Title III: Section 311/312
Fire hazard
Sudden release of pressure (explosion) hazard
Immediate health hazard
Delayed health hazard
- SARA Title III Section 313 and 40 CFR Part 372
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
None required per SARA TITLE III SECTION 313.
- TSCA Section 8(b) Inventory
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by us.
15.2 Canadian Regulations
- Workplace Hazardous Materials Information System (WHMIS)
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
CLASS D, DIV 2B
CLASS B, DIV 2
- Canadian Environmental Protection Act (CEPA)
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.
- National Pollutant Release Inventory (NPRI)
This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
None required.
16. Other Information
CL (Cautionary Labeling): Products bearing the CL (Cautionary
Labeling) Seal of The Art & Creative Materials Institute, Inc. (ACMI)
are certified to be properly labeled in a program of toxicological
evaluation by a medical expert. This program is reviewed by ACMI's
Toxicological Advisory Board. These products are certified by ACMI
to be labeled in accordance with the chronic hazard labeling
standard, ASTM D-4236 and Federal Law, P.L. 100-695.
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.
CUR ISSUE 14-JAN-04
PREVIOUS ISSUE: 30-AUG-01
